unfortunatley for NA, you cant just do one thing an expect performance. on a turbo car, sure, change bits here and there, it'll net you small gains.
by putting more fuel in, you need more air
to get more air, youll need the motor to be bigger or move faster.
doing this requires a cam or portnpolish or stronger bottom end, raised CR etc.
so i guess im saying feel free to do this, but in your current guise you wont see much. if you skim the head, put in a cam and valves/springs and retune it, then yeah your fuel rail and FPR will be worth it